Ligand Platforms in Homogenous Catalytic Reactions with Metals: Practice and Applications for Green Organic Transformations

Serving as a user?s manual for synthetic organic and catalytic chemists, this book guides chemists in the design and choice of ligands to catalyze organic reactions and apply the results for more efficient, green, and practical synthesis. • Focuses on the role of ligands in metal complexes that catalyze green organic transformations: a hot topic in the area of organic synthesis and green chemistry • Offers a comprehensive resource to help readers design and choose ligands and understand selectivity/reactivity characteristics • Addresses a gap by taking novel ligand approaches and including up–to–date discussion on hydrogen transfers and reactions • Presents important industrial perspective and provides rational explanations of ligand effects, impacts, and novelty INDICE: Preface Part I: N–Heterocyclic Carbene Ligands in Transition Metal Catalyzed Hydrogen Transfer and Dehydrogenative Reactions Chapter 1 Oxidation and Hydrogenation Reactions Catalyzed by Transition Metal Complexes Bearing N–Heterocyclic Carbene Ligands 1.1 Introduction 1.2 Oxidation of Alcohols Based on Hydrogen Transfer 1.3 Oxidation of Alcohols Based on Dehydrogenation 1.4 Hydrogenation and Transfer Hydrogenation of Carbon–Heteroatom Unsaturated Bonds 1.5 Other Related Hydrogenative Reactions 1.6 References Chapter 2 Bond Forming Reactions Catalyzed by Transition Metal Complexes Bearing N–Heterocyclic Carbene Ligands 2.1 Introduction 2.2 Carbon–Carbon Bond Formation Based on Hydrogen Transfer 2.3 Carbon–Nitrogen Bond Formation Based on Hydrogen Transfer and Dehydrogenation 2.4 Carbon–Oxygen Bond Formation Based on Hydrogen Transfer and Dehydrogenation 2.5 References Part II:  η 4 –Cyclopentadienone/ η 5 –Hydroxycyclopentadineyl and Related Ligands in Transition Metal Catalyzed Hydrogen Transfer and Dehydrogenative Reactions Chapter 3 Oxidation and Hydrogenation Reactions Catalyzed by Transition Metal Complexes Bearing η 4 –Cyclopentadienone/ η 5 –Hydroxycyclopentadineyl and Related Ligands 3.1 Introduction 3.2 Oxidation of Alcohols Based on Hydrogen Transfer and Dehydrogenation 3.3 Oxidation of Amines Based on Hydrogen Transfer and Dehydrogenation 3.4 Hydrogenation and Transfer Hydrogenation of Carbonyl Compounds 3.5 Hydrogenation and Transfer Hydrogenation of Imines and Related Compounds 3.5 References Chapter 4 Bond Forming Reactions Catalyzed by Transition Metal Complexes Bearing η 4 –Cyclopentadienone/ η 5 –Hydroxycyclopentadineyl and Related Ligands 4.1 Introduction 4.2 Carbon–Nitrogen Bond Formation Based on Hydrogen Transfer and Dehydrogenation 4.3 Carbon–Oxygen Bond Formation Based on Hydrogen Transfer and Dehydrogenation 4.4 Carbon–Carbon Bond Formation Based on Hydrogen Transfer 4.5 References Part III: Pincer Ligands in Transition Metal Catalyzed Hydrogen Transfer and Dehydrogenative Reactions Chapter 5 Dehydrogenation of Alkanes Catalyzed by Transition Metal Complexes Bearing Pincer Ligands 5.1 Introduction 5.2 Conversion of Alkanes into Alkenes Based on Hydrogen Transfer 5.3 Dehydroaromatization of Alkanes Based on Hydrogen Transfer 5.4 Alkane Methathesis by Tandem Alkane Dehydrogenation and Alkene Methathesis 5.5 Conversion of Alkanes into Alkenes Based on Dehydrogenation 5.6 References Chapter 6 Oxidation and Hydrogenation Reactions Catalyzed by Transition Metal Complexes Bearing Pincer Ligands 6.1 Introduction 6.2 Oxidation of Alcohols Based on Hydrogen Transfer and Dehydrogenation 6.3 Dehydrogenation of Amines 6.4 Hydrogenation and Transfer Hydrogenation of Carbon–Heteroatom Unsaturated Bonds 6.5 References Chapter 7 Bond Forming Reactions Catalyzed by Transition Metal Complexes Bearing Pincer Ligands 7.1 Introduction 7.2 Carbon–Carbon Bond Formation Based on Hydrogen Transfer 7.3 Carbon–Nitrogen Bond Formation Based on Hydrogen Transfer and Dehydrogenation 7.4 Carbon–Oxygen Bond Formation Based on Hydrogen Transfer and Dehydrogenation 7.5 References Part IV: Bidentate and Miscellaneous Ligands in Transition Metal Catalyzed Hydrogen Transfer and Dehydrogenative Reactions Chapter 8 Oxidation and Dehydrogenation of Alcohols and Amines Catalyzed by Well–Defined Transition Metal Complexes Bearing Bidentate and Miscellaneous Ligands 8.1 Introduction 8.2 Oxidation of Alcohols Based on Hydrogen Transfer with Oxidant 8.3 Dehydrogenative Oxidation of Alcohols without Oxidant 8.4 Oxidation of Amines Based on Hydrogen Transfer and Dehydrogenation 8.5 References Chapter 9 Hydrogenation and Transfer Hydrogenation of Carbon–Heteroatom Unsaturated Bonds Catalyzed by Well–Defined Transition Metal Complexes Bearing Bidentate and Miscellaneous Ligands 9.1 Introduction 9.2 Hydrogenation and Transfer Hydrogenation of Carbonyl and Related Compounds 9.3 Hydrogenation and Transfer Hydrogenation of Imines and Related Compounds 9.4 References Chapter 10 Bond Forming Reactions Based on Hydrogen Transfer Catalyzed by Well–Defined Transition Metal Complexes Bearing Bidentate and Miscellaneous Ligands 10.1 Introduction 10.2 Carbon–Carbon Bond Formation Based on Hydrogen Transfer 10.3 Carbon–Nitrogen Bond Formation Based on Hydrogen Transfer and Dehydrogenation 10.4 Carbon–Oxygen Bond Formation Based on Hydrogen Transfer and Dehydrogenation 10.5 References

• ISBN: 978-1-118-20351-4
• Editorial: Wiley–Blackwell
• Encuadernacion: Cartoné
• Páginas: 368
• Fecha Publicación: 19/12/2014
• Nº Volúmenes: 1
• Idioma: Inglés