The P-H group, a functional group per the IUPAC definition, is unique in chemistry. It is included in the molecules of both inorganic and organic compounds of phosphorus, both trivalent and pentavalent phosphorous compounds, and as such is one of the most powerful groups for organic synthesis, with practical applications and considerable potential for synthesis, polymer chemistry, medicinal chemistry, and more. P-H Group Reactivity describes this bridge between inorganic and organic phosphorus compounds, and provides a basis to explore the myriad possibilities for synthesis of novel low and high molecular phosphorus-containing compounds. The book covers well-documented reactions in detail, including: tautomerization; oxidation; reduction; alkylation; oxidation coupling; addition reaction to: carbon-carbon multiple bonds, Schiff base, isocyanates, nitriles, epoxides; addition to carbonyl group, Kabachnik- Fields reaction; cross-coupling reaction; C - H activation reaction; transfer hydrogenation; and redactive phosphination process. In an accessible style complete with synthetic routes and figures, the resource then covers the reactivity of multiple P-H group members: phosphines; phosphine oxides; hypophosphorus acid; H-phosphinic acids; and poly(alkylene H-phosphonate)s. This valuable coverage supports the advancement of research and applications in this area, for scientists solving a scientific problem or starting a variety of new projects such as, a new reaction for the synthesis of biologically active compounds; new methods of polymer synthesis; or new methodology for polymer modification. Describes the diverse reactivity of the phosphorus-hydrogen group, perhaps the most powerful in organic chemistryIncludes practical information for the synthesis of catalysts, biologically active substances, flame retardants, advance materials, polymer materialsOffers a visually-accessible guide to important reactions by an internationally recognized chemist INDICE: 1. Acidity and tautomerization of P - H group2. Reactivity of P-H group of phosphines3. Reactivity of P-H group of phosphine oxides4. Reactivity of P-H group of hypophosphorus acid 5. Reactivity of P-H group of H-phosphinic acids6. Reactivity of P-H group of H-phosphonic acid 7. Reactivity of P-H group of poly(alkylene H-phosphonate)s
- ISBN: 978-0-12-813834-2
- Editorial: Academic Press
- Encuadernacion: Rústica
- Páginas: 425
- Fecha Publicación: 01/09/2017
- Nº Volúmenes: 1
- Idioma: Inglés