Terpyridine-based materials: for catalytic, optoelectronic and life science applications

INDICE: Preface ix List of Abbreviations xi 1 Introduction 1 2 Synthesis, Properties, and Applications of Functionalized 2,2u:6u,2v-Terpyridines 13 2.1 Introduction 13 2.2 Basic Synthetic Strategies 13 2.2.1 Ring-Assembly Methodologies 14 2.2.2 Cross-Coupling Procedures 18 2.3 Synthesis and Properties of 2,2u:6u,2v-Terpyridine Derivatives 19 2.3.1 4u-Substituted 2,2u:6u,2v-Terpyridinoxy Derivatives 19 2.3.2 Miscellaneous 4u-Substituted 2,2u:6u,2v-Terpyridine Derivatives 24 2.4 2,2u:6u,2v-Terpyridines Symmetrically Substituted on the Outer Pyridine Rings 28 2.5 Ziessel-Type 2,2u:6u,2v-Terpyridines 31 2.6 Kro¨hnke-Type 2,2u:6u,2v-Terpyridines 38 2.7 Miscellaneous Terpyridine-Analogous Compounds 49 2.7.1 Rigid U- and S-Shaped Terpyridines 49 2.7.2 Five-Membered N-Heterocycles Replacing the Outer Pyridine Rings 51 2.7.3 The Swedish Concept: Expanded Bite Angles in Tridentate Ligands 53 3 Chemistry and Properties of Terpyridine Transition Metal Ion Complexes 65 3.1 Introduction 65 3.2 Basic Synthetic Strategies and Characterization Tools 66 3.3 RuII and OsII Complexes 73 3.3.1 Synthesis of RuII and OsII Bis(terpyridine) Complexes 73 3.3.2 RuII Ions and Terpyridine Ligands A Happy Marriage? 75 3.3.2.1 Photophysical Properties 75 3.3.2.2 Mononuclear RuII Bis(terpyridine) Complexes 76 3.3.2.3 Oligonuclear Complexes Containing RuII/OsII Bis(terpyridine) Units 89 3.3.2.4 Dendritic and Star-Shaped Systems Containing RuII Bis(terpyridine) Units 102 3.4 Iridium(III) Complexes with Terpyridine Ligands 107 3.5 Platinum(II) Mono(terpyridine) Complexes 115 4 Metallo-Supramolecular Architectures Based on Terpyridine Complexes129 4.1 Introduction 129 4.2 Terpyridine-Containing Metallo-Macrocycles 130 4.3 The HETTAP Concept 148 4.4 Racks and Grids 154 4.5 Helicates 171 4.6 Rotaxanes and Catenanes 177 4.7 Miscellaneous Structures 182 4.7.1 Cyclodextrin Derivatives 182 4.7.2 Other Assemblies 185 5 p-Conjugated Polymers Incorporating Terpyridine Metal Complexes 199 5.1 Introduction 199 5.2 Metallo-SupramolecularPolymerization 200 5.3 Metallopolymers Based on p-Conjugated Bis(terpyridine)s 204 5.3.1 Polymerization by Transition Metal Ion Coordination 204 5.3.2 Self-Assembly of Metallopolymers 212 5.3.3 Chiral Metallopolymers 219 5.3.4 Non-Classical Metallopolymers 220 5.3.5 Polymerization Using the Complex First Method 224 5.4 Main-Chain Metallopolymers Based on Terpyridine-Functionalized p-Conjugated Polymers 229 6 Functional Polymers Incorporating Terpyridine-Metal Complexes 241 6.1 Introduction 241 6.2 Polymers with Terpyridine Units in the Side-Chain 242 6.2.1 Materials Based on Flexible Organic Polymers 242 6.2.2 Materials Based on p-Conjugated Polymers 257 6.3 Polymers with Terpyridines within the Polymer Backbone 262 6.3.1 Polymers from Organic Small-Molecule Building Blocks 263 6.3.2 Chain-Extended Polymers from Polymeric Building Blocks 269 6.3.3 Monotopic Macroligands by End-Group Functionalization 272 6.3.4 Functional Terpyridine-Containing Initiators 277 6.3.4.1 I

• ISBN: 978-3-527-33038-6
• Editorial: Wiley-VCH
• Encuadernacion: Cartoné
• Páginas: 542
• Fecha Publicación: 05/10/2011
• Nº Volúmenes: 1
• Idioma: Inglés