Fundamentals of Soft Interfaces in Colloid and Surface Chemistry

Fundamentals of Soft Interfaces in Colloid and Surface Chemistry, Volume 37 explains and summarizes the fundamentals of soft interfaces and soft particles from a colloid and surface chemistry standpoint, bringing knowledge together into a single resource for the first time. The book provides detailed mathematical descriptions of colloidal and interfacial systems, with a particular emphasis on ionic, electrokinetic, and electrostatic phenomena. The author covers the most recent theoretical advances in the field of electrostatic interactions between soft interfaces, electrophoresis, diffusiophoresis, gel electrophoresis of soft particles including ionic size effects, ion-partitioning effects, and the effects of hydrodynamic slip on hydrophobic surfaces. This book will help readers by providing a range of approximate analytic formulas which can be used to interpret various interfacial phenomena of soft interfaces and analyze experimental data in various fields. It is written for graduate students and researchers chiefly in chemistry but also chemical engineering, physics, and materials science. Utilizes rigorous theories and various useful approximate analytical formulas based upon themProvides a detailed mathematical description of colloidal and interfacial systems, with a particular emphasis on ionic and electrostatic phenomenaDescribes basic theories for various electrostatic and electrokinetic phenomena of soft interfacesPresents many formulas used to interpret and analyze experimental data of soft interfaces INDICE: Part I: Charge and potential at soft interfaces1. Poisson-Boltzmann equation for a potential distribution around a charged surface2. Effects of ionic size: modified Poisson-Boltzmann equation3. Ion size effect on charge and potential relationship4. Discrete charge effectPart II: Interaction between two colloidal particles5. Electrostatic interaction between two hard particles6. Ionic size effect on the electrostatic interaction between two particles7. Electrostatic Interaction between two soft particles8. van der Waals interaction between two particles9. DLVO theory of colloid stability10. Non-DLVO interactions11. Total interaction energy between two polymer-coated particlesPart III: Electrokinetics of soft particles12. Electrophoresis: motion of colloidal particles in an electric field13. General theory of electrophoresis of soft particles14. Electrophoresis of a soft particle: Analytic approximations15. Effects of hydrodynamic liquid slip-on hydrophobic surfaces16. Transient electrophoresis and dynamic electrophoresis17. Gel electrophoresis: electrophoresis of colloidal particles in a polymer gel medium18. Gel electrophoresis of a soft particle: Analytic approximations19. Diffusiophoresis: motion of colloidal particles in an electrolyte concentration gradient20. Diffusiophoresis of soft particlesPart IV: Ion transport and ion adsorption at soft interfaces21. Membrane transport with time delay22. Membrane potential23. Ion-adsorption effect on the interfacial tension at soft interfaces

• ISBN: 978-0-443-16116-2
• Editorial: Academic Press
• Encuadernacion: Rústica
• Páginas: 368
• Fecha Publicación: 02/09/2024
• Nº Volúmenes: 1
• Idioma: Inglés