Advanced potentiometry: potentiometric titrations and their systematic errors

Advanced Potentiometry details the accurate calculation of potentiometric titrations. Additional terms such as the ideal diffusion potential together with the contribution of activity factors furnish calculated stability constants which do not include systematic errors and thus present a complete and correct description of equilibrium processes. Moreover, serious systematic errors resulting from the recent use of curve-fitting computer programs are highlighted later in the text. Advanced Potentiometry can advantageously be used by lecturers, researchers, PhD graduates and undergraduate students working in the fieldsof Solution Chemistry, Physical Chemistry, Inorganic Chemistry and AnalyticalChemistry and Environmental Research. Provides a platform for the accurate interpretation of potentiometric titration data Only recent monograph on the market to accurately present the calculation of stability constants and equilibrium processes without systematic errors INDICE: Preface.- 1. Introduction.- 2. Emf cells with mixtures of strong electrolytes and liquid junctions of the type AY a AY + HY + BYz(B).- 3. Determination of the ionic molar conductivities in mixtures of the strong electrolytes HClO4 + NaClO4 + Cd(ClO4)2.- 4. Studies on emf cells where complex formation takes place using liquid junctions of the type AY a AY + HY + BYz(B) + AyL and - log10 [H+] 7.- 5. Estimation of the total potential anomalies and the determination of the equilibrium constants in emf cells where every kind of complex can be present.- 6. On emf titrations proposed for the determination of some interaction coefficients.- 7. Emf titrations proposed for the determination of certain transport numbers.- 8. Studies on emf cells where strong complexes are formed using liquid junctions of the type AY a AY + BYz(B) + HY + AyL at [Y-] = C M, constant, and - log10 [H+] 7.

• ISBN: 978-1-4020-9524-5
• Editorial: Springer
• Encuadernacion: Cartoné
• Páginas: 350
• Fecha Publicación: 01/03/2009
• Nº Volúmenes: 1
• Idioma: Inglés