For fifty years, Hydrosilylation has been one of the most fundamental and elegant methods for the laboratory and industrial synthesis of organosilicon and silicon related compounds. Despite the intensive research and continued interest generated by organosilicon compounds, no comprehensive book incorporating its various aspects has been published this century. The aim of this book is tocomprehensively review the advances of hydrosilylation processes since 1990. The survey of the literature published over the last two decades enables the authors to discuss the most recent aspects of hydrosilylation advances (catalytic and synthetic) and to elucidate the reaction mechanism for the given catalyst used and the reaction utilization. New catalytic pathways under optimum conditions necessary for efficient synthesis of organosilicon compounds are presented. This monograph shows the extensive development in the application of hydrosilylation in organic and asymmetric syntheses and in polymer and material science. Dedicated to the field of hydrosilylation in 15 years Convey a complete literature review of the most important mechanistic, structural, and synthetic developments in the field to date Marks the 60th anniversary of the first reported hydrosilylation reaction and the 50th anniversary of the Spier Catalyst discovery INDICE: I. Catalytic aspects of hydrosilylation: Free-radical addition.- II. The reactivity in hydrosilylation of particular types of organic compounds with multiple bonds: Hydrocarbons with an isolated C=C bond.- III. The reactivity in hydrosilylation of particular types of silicon hydrides.- IV. The hydrosilylation of unsaturated organosilicon compounds.- V. Products and applications: Silanes as coupling agents.
- ISBN: 978-1-4020-8171-2
- Editorial: Springer
- Encuadernacion: Cartoné
- Páginas: 410
- Fecha Publicación: 01/10/2008
- Nº Volúmenes: 1
- Idioma: Inglés