Silicon is the second most abundant chemical element in the Earth's crust (about 25 mass %) after oxygen. Accordingly, organosilicon chemistry, dealing with compounds containing carbon-silicon bonds, is an essential part of organic and organometallic chemistry, and organosilicon compounds are widely encountered in commercial products such as in the fabrication of sealants, adhesives, and coatings. Although the spectacular progress in organosilicon chemistry has been well documented in several books that were published over the past decades, the time has now come to refresh and update the current state of affairs in the field, where many milestone discoveries have been reported during the last few years. This is the main purpose of the proposed book, which is planned to provide its readers with a description of the state-of-the-art status of organosilicon chemistry, including its theoretical, synthetic, physico-chemical, and applied aspects. Providing high quality content in a key strategic signing area, this work is strong addition to our chemistry offerings for organic, Main group, and organometallic researchers. Features valuable contributions from prominent experts cover both fundamental (theoretical, synthetic, physico-chemical) and applied (material science, applications) aspects of modern organosilicon chemistryCovers important breakthroughs in the field as well as with the historically significant achievements of the pastIncludes applied information for a wide range of specialists from junior and senior researchers (from both academia and industry), working in organometallic, organosilicon, main group element, transition metal, and industrial silicon chemistry, as well as those from interdisciplinary fields such as polymer, material science, nanotechnology INDICE: Volume 1 Chapter I.1. Nonclassical Organosilicon Compounds Chapter II.1.1.1. Transition Metal Complexes of Silicon (excluding silylene complexes) Chapter II.1.1.2. Silicon Cages and Clusters Chapter II.1.1.3. Chiral Organosilicon Compounds Chapter II.1.2.1. Silicon-Centered Cations Chapter II.1.2.2. Silicon-Centered Radicals Chapter II.1.2.3. Silicon-Centered Anions Chapter II.1.2.4. Silylenes and Their Transition Metal Complexes Chapter II.1.2.5. Multiple Bonds to Silicon Chapter II.1.2.6. Silaaromatics and Related Compounds Chapter II.1.3.1. Penta - and Hexacoordinated Silicon(IV) Compounds Volume 2 Chapter II.2.1. X-Ray Crystallography of Organosilicon Compounds Chapter II.2.2. 29Si NMR Spectroscopy Chapter II.2.3. Thermochemistry of Organosilicon Compounds Chapter II.2.4. Photoelectron Spectroscopy of Organosilicon Compounds Chapter III.1. Hydrosilylation of the Carbon-Carbon Multiple Bonds Chapter III.2. Polysilanes Chapter III.3. Siloxanes and Silicones Chapter III.5. Silicon-Based Dendrimers and Irregular Hyperbranched Polymers
- ISBN: 978-0-12-814329-2
- Editorial: Academic Press
- Encuadernacion: Rústica
- Páginas: 1000
- Fecha Publicación: 01/10/2017
- Nº Volúmenes: 1
- Idioma: Inglés