With its impressive features, gold has added another facet to organic catalysis. Focusing on homogeneous catalysis this book also covers the main applications in heterogeneous catalysis.Following a look at the gold-catalyzed additionof heteroatom nucleophiles to alkynes, this monograph goes on to discuss gold-catalyzed additions to allenes and alkenes, gold-catalyzed benzannulations, cycloisomerization and rearrangement reactions, as well as oxidation and reduction reactions. The whole is finished off with a section on gold-catalyzed aldol and related reactions and the application of gold-catalyzed reactions to natural product synthesis. INDICE: GOLD-CATALYZED ADDITION OF HETEROATOM NUCLEOPHILES TO ALKYNESGold-Alkyne ComplexesHydrochlorinationHydrationHydroalkoxylationHydroaminationHydrothiloationCyclization to Aromatic HeterocyclesGOLD-CATALYZED ADDITIONS TO ALLENESGold-Allene ComplexesO-NucleophilesN-NucleophilesS-NucleophilesGOLD-CATALYZED ADDITIONS TO ALKENESGold-Alkene ComplexesO-NucleophilesN-NucleophilesGOLD-CATALYZED BENZANNULATIONSGOLD-CATALYZED CYCLOISOMERIZATION AND REARRANGEMENT REACTIONSEnyne Cyclization and Related CycloisomerizationsRearrangement of Propargyl Esters, Amides and Related SubstratesSigmatropic RearrangementsGOLD-CATALYZED OXIDATION REACTIONSOxidation of AlkenesOxidation of AlcoholsGOLD-CATALYZED REDUCTION REACTIONSHydrogenation of C-C Multiple BondsReduction of C-O Double BondsReduction of Nitro CompoundsGOLD-CATALYZED ALDOL AND RELATED REACTIONSAldol ReactionsMannich ReactionsMichael AdditionsAPPLICATION OF GOLD-CATALYZED REACTIONS TO NATURAL PRODUCT SYNTHESIS
- ISBN: 978-3-527-31952-7
- Editorial: Wiley-VCH
- Encuadernacion: Cartoné
- Páginas: 418
- Fecha Publicación: 18/04/2012
- Nº Volúmenes: 1
- Idioma: Inglés