Modern Synthesis Processes and Reactivity of Fluorinated Compounds: Progress in Fluorine Science

Modern Synthesis Processes and Reactivity of Fluorinated Compounds focuses on the exceptional character of fluorine and fluorinated compounds. This comprehensive work explores examples taken from all classes of fluorine chemistry and illustrates the extreme reactivity of fluorinating media and the peculiar synthesis routes to fluorinated materials. It provides advanced and updated information on the latest synthesis routes to fluorocompounds and on the involved reaction mechanisms. Special attention is given to the unique reactivity of fluorine and fluorinated media as well as the correlation of those properties to valuable applications of fluorinated compounds. Quality content edited and contributed by leading scholars in the fieldApplied guidance on the preparation of original fluorinated compounds, potentially transferable from the lab scale to industrial applicationsPractical synthesis information for a wide audience interested in fluorine compounds in many branches of chemistry, materials science, and physics INDICE: 1. The Origin of Fluorine2. The fluorine atom in healthcare and agrochemical applications - a contribution to life science3. Industrial syntheses of HydroFluoroOlefins and related products4. Electrochemical fluorination: a powerful tool for the preparation of organo-fluorine compounds5. Review on the Langlois reagent?6. Fluorinated reagents in organic synthesis: from trifluoromethylation to trifluoromethylthiolation  7. Nucleophilic di- and trifluoromethylation of C=N and C=O bonds8. Oxidative Trifluoromethylation and Trifluoromethylthiolation9. Advances in catalytic enantioselective carbon-fluorine bond formation10. Development of electrophilic perfluoroalkylating reagents11. New nucleophilic fluoroalkylation12. Micro reactor technology as tool for selective fluorination in organic chemistry13. Superacidic reactions14. Photoredox-induced trifluoromethylation15. Side-chain fluorination in peptides16. Ionic liquids and polymers for battery and fuel cells17. Strategic Incorporation of Fluorine for Drug Discovery and Preclinical Drug Development18. Telomerization of Fluoroalkenes and Applications19. High oxidation states in metal fluorides20. Photochemical syntheses of fluorides in liquid anhydrous hydrogen fluoride21. Sol-gel synthesis of metal fluorides: reactivity and mechanisms22. Synthesis routes and reaction mechanisms toward new metal fluorides23. Ionic liquid materials based on fluoroanions24. Surface Fluorination & surface reactivity25. Chemical and electrochemical stability of copper in molten KF-2HF

• ISBN: 978-0-12-803740-9
• Editorial: Elsevier
• Encuadernacion: Rústica
• Páginas: 750
• Fecha Publicación: 01/11/2016
• Nº Volúmenes: 1
• Idioma: Inglés