Catalytic Hydroarylation of Carbon-Carbon Multiple Bonds

Filling a gap in the literature, this book comprehensively reviews catalytic C–H addition reactions of (hetero)aromatic hydrocarbons across carbon–carbon multiple bonds. In so doing, it summarizes both the scope as well as the limitations of different catalyst systems and building blocks, while highlighting their application to the synthesis of pharmaceuticals as well as commodity chemicals. Focusing on the latest developments, the team of authors comprising leaders in the field covers such topics as the hydroarylation of olefins, alkyne hydroarylation in the presence of transition metal catalysts, reaction of alkynes with arylboronic acids, and allene hydroarylation, as well as the synthesis of functionalized arenes and heteroaromatics. A must–have for synthetic chemists in academia and industry dealing with catalysis, organometallic chemistry, the synthesis of natural products, fine chemicals, pharmaceuticals, products of the chemical industry and organic materials. INDICE: 1) Functionalization of Heteroaromatic Substrates using Group 9 and 10 Catalysts. 2) Ruthenium Catalysts for the Alkylation of Functionalized Arenes and Heteroaromatic Substrates via Hydroarylation. 3) Alkylation of Arenes Without Chelation Assistance: Transition Metal Catalysts with d6 Electron Configurations. 4) Hydroarylation of Olefins with Complexes Bearing d8 Metal Centers. 5) Hydroarylation of C–C Multiple Bonds using Nickel Catalysts. 6) Hydroarylation of Alkynes and Alkenes using Group 7 –. 9 First Row Transition Metal Catalysts. 7) Hydroarylation of Alkynes using Cu, Ag and Au Catalysts. 8) Catalytic Alkyne Hydroarylation Using Arylboron Reagents, Aryl Halides, and Congeners. 9) Transition Metal–Catalyzed Hydroarylation of Allenes

• ISBN: 978-3-527-34013-2
• Editorial: Wiley VCH
• Encuadernacion: Cartoné
• Páginas: 392
• Fecha Publicación: 29/11/2017
• Nº Volúmenes: 1
• Idioma: Inglés